| 99* | TW Hayward | Surrey v Essex | County Ground, Leyton | 1900 | f5396 |
| 99* | AO Jones | Nottinghamshire v Surrey | Kennington Oval, Kennington | 1901 | f5671 |
| 99* | RT Crawford | Leicestershire v Worcestershire | Aylestone Road, Leicester | 1902 | f5929 |
| 99* | RE Foster | Worcestershire v Somerset | County Ground, Taunton | 1905 | f6736 |
| 99* | JWH Makepeace | Lancashire v Sussex | The Saffrons, Eastbourne | 1907 | f7213 |
| 99* | CB Fry | Sussex v Worcestershire | County Ground, Hove | 1907 | f7223 |
| 99* | GW Hodgkinson | Somerset v Gloucestershire | County Ground, Taunton | 1910 | f7928 |
| 99* | JC Hubble | Kent v Hampshire | Dean Park, Bournemouth | 1914 | f9267 |
| 99* | JJ Bridges | Somerset v Essex | Clarence Park, Weston-super-Mare | 1919 | f9474 |
| 99* | E Oldroyd | Yorkshire v Hampshire | Bramall Lane, Sheffield | 1921 | f9886 |
| 99* | JW Hearne | Middlesex v Lancashire | Old Trafford, Manchester | 1922 | f10191 |
| 99* | J Hardstaff | Nottinghamshire v Glamorgan | Cardiff Arms Park, Cardiff | 1922 | f10295 |
| 99* | BW Quaife | Warwickshire v Northamptonshire | Edgbaston, Birmingham | 1923 | f10689 |
| 99* | RA Sinfield | Gloucestershire v Hampshire | Dean Park, Bournemouth | 1932 | f13979 |
| 99* | J O'Connor | Essex v Middlesex | Vista Road Recreation Ground, Clacton-on-Sea | 1934 | f14707 |
| 99* | EH Hendren | Middlesex v Lancashire | Old Trafford, Manchester | 1935 | f15059 |
| 99* | DF Walker | Hampshire v Somerset | Rowdens Road, Wells | 1937 | f15864 |
| 99* | WW Keeton | Nottinghamshire v Kent | Trent Bridge, Nottingham | 1937 | f15876 |
| 99* | WA Hill | Warwickshire v Lancashire | Edgbaston, Birmingham | 1939 | f16478 |
| 99* | AH Dyson | Glamorgan v Gloucestershire | Rodney Parade, Newport | 1939 | f16499 |
| 99* | L Hutton | Yorkshire v Glamorgan | Bramall Lane, Sheffield | 1946 | f17178 |
| 99* | L Hutton | Yorkshire v Leicestershire | Bramall Lane, Sheffield | 1948 | f18076 |
| 99* | JF Crapp | Gloucestershire v Surrey | Kennington Oval, Kennington | 1949 | f18336 |
| 99* | WGA Parkhouse | Glamorgan v Essex | Rodney Parade, Newport | 1952 | f19714 |
| 99* | LF Outschoorn | Worcestershire v Glamorgan | Tipton Road, Dudley | 1954 | f20473 |
| 99* | JV Wilson | Yorkshire v Gloucestershire | Headingley, Leeds | 1959 | f22837 |
| 99* | R Booth | Worcestershire v Lancashire | Old Trafford, Manchester | 1960 | f23248 |
| 99* | HL Johnson | Derbyshire v Sussex | The Manor Sports Ground, Worthing | 1961 | f23966 |
| 99* | DNF Slade | Worcestershire v Gloucestershire | Wagon Works Ground, Gloucester | 1962 | f24389 |
| 99* | RM Prideaux | Northamptonshire v Derbyshire | County Ground, Derby | 1964 | f25227 |
| 99* | MC Cowdrey | Kent v Gloucestershire | Crabble Athletic Ground, Dover | 1965 | f25969 |
| 99* | P Willey | Northamptonshire v Somerset | County Ground, Taunton | 1970 | f28242 |
| 99* | B Leadbeater | Yorkshire v Kent | North Marine Road, Scarborough | 1974 | f30266 |
| 99* | RL Ollis | Somerset v Gloucestershire | Phoenix County Ground, Bristol | 1983 | f34630 |
| 99* | P Bainbridge | Gloucestershire v Kent | Phoenix County Ground, Bristol | 1983 | f34655 |
| 99* | SG Hinks | Kent v Sussex | The Saffrons, Eastbourne | 1985 | f35884 |
| 99* | RJ Bailey | Northamptonshire v Leicestershire | County Ground, Northampton | 1985 | f35926 |
| 99* | GW Humpage | Warwickshire v Leicestershire | Leicester Road, Hinckley | 1987 | f37126 |
| 99* | CM Wells | Sussex v Somerset | County Ground, Taunton | 1990 | f38723 |
| 99* | DA Reeve | Warwickshire v Yorkshire | Edgbaston, Birmingham | 1991 | f39350 |
| 99* | RJ Harden | Somerset v Nottinghamshire | Trent Bridge, Nottingham | 1993 | f40592 |
| 99* | RC Russell | Gloucestershire v Derbyshire | College Ground, Cheltenham | 1993 | f40612 |
| 99* | NR Taylor | Kent v Nottinghamshire | Trent Bridge, Nottingham | 1995 | f41799 |
| 99* | DM Jones | Derbyshire v Kent | St Lawrence Ground, Canterbury | 1997 | f43044 |
| 99* | CJ Adams | Sussex v Surrey | The Foster's Oval, Kennington | 1998 | f43803 |
| 99* | G Welch | Derbyshire v Somerset | County Ground, Taunton | 2005 | f48824 |
| 99* | SM Davies | Worcestershire v Gloucestershire | College Ground, Cheltenham | 2008 | f50901 |
| 99* | NM Carter | Warwickshire v Nottinghamshire | Edgbaston, Birmingham | 2010 | f52493 |
| 99* | EJH Eckersley | Leicestershire v Hampshire | The Ageas Bowl, Southampton | 2013 | f54789 |
| 99* | WRS Gidman | Kent v Sussex | The 1st Central County Ground, Hove | 2016 | f57236 |
| 99* | MJ Richardson | Durham v Hampshire | The Ageas Bowl, Southampton | 2016 | f57257 |
| 99* | GK Berg | Hampshire v Yorkshire | The Ageas Bowl, Southampton | 2017 | f57879 |
| 99* | BWM Mike | Leicestershire v Middlesex | Lord's Cricket Ground, St John's Wood | 2022 | f60837 |
| 99* | WT Root | Glamorgan v Worcestershire | County Ground, New Road, Worcester | 2022 | f60906 |
| 99* | MJJ Critchley | Essex v Warwickshire | The Cloud County Ground, Chelmsford | 2024 | f62261 |
