| 165* | CDJ Dent | Gloucestershire Second XI v Warwickshire Second XI | The Common, Rockhampton | 2024 |
| 153 | LPJ Kimber | Leicestershire Second XI v Lancashire Second XI | Stanley Park, Blackpool | 2025 |
| 149 | CG Benjamin | Warwickshire Second XI v Glamorgan Second XI | Spytty Park, Newport | 2021 |
| 144 | RS Bopara | Sussex Second XI v Middlesex Second XI | Old Deer Park, Richmond | 2023 |
| 132* | MS Pepper | Essex Second XI v Marylebone Cricket Club Young Cricketers | Hare Field, Coggeshall | 2019 |
| 132* | JL Smith | Surrey Second XI v Kent Second XI | Polo Farm Sports Club, Canterbury | 2021 |
| 132* | TR Bevan | Glamorgan Second XI v Middlesex Second XI | Arundel Castle Cricket Club Ground, Arundel | 2022 |
| 129 | RS Patel | Surrey Second XI v Middlesex Second XI | Old Deer Park, Richmond | 2025 |
| 127* | JJ Roy | Surrey Second XI v Sussex Second XI | Spen Cama Memorial Ground, Fulking | 2013 |
| 125 | GS Ballance | Yorkshire Second XI v Lancashire Second XI | Aigburth, Liverpool | 2021 |
| 124* | AGH Orr | Sussex Second XI v Essex Second XI | The 1st Central County Ground, Hove | 2022 |
| 124 | JB Cracknell | Middlesex Second XI v Surrey Second XI | Old Deer Park, Richmond | 2025 |
| 122* | RS Bopara | Essex Second XI v Somerset Second XI | Taunton Vale Sports Club Ground, Taunton | 2019 |
| 122* | ZB Lion-Cachet | Sussex Second XI v Middlesex Second XI | Uxbridge Cricket Club Ground, Uxbridge | 2025 |
| 120* | TC Fell | Worcestershire Second XI v Yorkshire Second XI | Windy Hill Lane, Marske-by-the-Sea | 2018 |
| 120 | LWP Wells | Lancashire Second XI v Derbyshire Second XI | Emirates Old Trafford, Manchester | 2023 |
| 118 | NRD Compton | Somerset Second XI v Glamorgan Second XI | Diamond Ground, Cardiff | 2012 |
| 118* | BBA Geddes | Surrey Second XI v Kent Second XI | London School of Economics Sports Ground, New Malden | 2022 |
| 118* | NR Welch | Leicestershire Second XI v Nottinghamshire Second XI | Gorse Lane, Grantham | 2022 |
| 117 | MS Pepper | Essex Second XI v Hampshire Second XI | The Ageas Bowl, Southampton | 2022 |
| 116 | PR Stirling | Middlesex Second XI v Hampshire Second XI | The Ageas Bowl (Nursery), Southampton | 2015 |
| 116* | AZ Lees | Yorkshire Second XI v Northamptonshire Second XI | Britannia Ground, Pudsey | 2017 |
| 116 | CR Brathwaite | Warwickshire Second XI v Glamorgan Second XI | Edgbaston Foundation Community Sports Ground, Birmingham | 2021 |
| 116* | GW Thomas | Somerset Second XI v Warwickshire Second XI | Edgbaston Foundation Community Sports Ground, Birmingham | 2023 |
| 116* | LJ Evans | Surrey Second XI v Kent Second XI | Polo Farm Sports Club, Canterbury | 2024 |
| 115 | GJ Maxwell | Hampshire Second XI v Marylebone Cricket Club Young Cricketers | Denis Compton Oval, Shenley | 2012 |
| 115* | SM Ervine | Hampshire Second XI v Middlesex Second XI | Old Deer Park, Richmond | 2018 |
| 115* | NJ Selman | Glamorgan Second XI v Nottinghamshire Second XI | Arundel Castle Cricket Club Ground, Arundel | 2019 |
| 115* | BJJ Wells | Gloucestershire Second XI v Warwickshire Second XI | College Ground, Cheltenham | 2022 |
| 114 | SG Budinger | Nottinghamshire Second XI v Derbyshire Second XI | Repton School Ground, Repton | 2021 |
| 114* | D Ferreira | Yorkshire Second XI v Lancashire Second XI | Shaw Lane, Barnsley | 2024 |
| 113* | JP Webb | Warwickshire Second XI v Somerset Second XI | County Ground, Taunton | 2014 |
| 113* | HRC Came | Derbyshire Second XI v Durham Second XI | Emirates Riverside, Chester-le-Street | 2021 |
| 113* | WAR Fraine | Yorkshire Second XI v Nottinghamshire Second XI | Worksop College Ground, Worksop | 2023 |
| 113* | WTE Smale | Glamorgan Second XI v Northamptonshire Second XI | Stowe School Ground, Stowe | 2023 |
| 113 | SIM King | Nottinghamshire Second XI v Derbyshire Second XI | Repton School Ground, Repton | 2025 |
| 112* | AST West | Unicorns v Middlesex Second XI | Anglo-American Playing Fields, Saffron Walden | 2014 |
| 112 | MDE Holden | Middlesex Second XI v Essex Second XI | Brunton Memorial Ground, Radlett | 2018 |
| 111 | BM Shafayat | Hampshire Second XI v Kent Second XI | The Ageas Bowl, Southampton | 2012 |
| 111 | LJ Evans | Warwickshire Second XI v Gloucestershire Second XI | Grange Road, Olton | 2013 |
| 111* | BJJ Wells | Somerset Second XI v Northamptonshire Second XI | Taunton Vale Sports Club Ground, Taunton | 2021 |
| 111 | EJ Pollock | Worcestershire Second XI v Gloucestershire Second XI | Visit Worcestershire New Road, Worcester | 2024 |
| 110 | K Ali | Leicestershire Second XI v Unicorns A | Grace Road, Leicester | 2012 |
| 110* | T Kohler-Cadmore | Worcestershire Second XI v Glamorgan Second XI | Chester Road North, Kidderminster | 2014 |
| 110* | AJ Hose | Marylebone Cricket Club Young Cricketers v Surrey Second XI | The Ridge, Purley | 2015 |
| 110 | NRT Gubbins | Middlesex Second XI v Essex Second XI | Brunton Memorial Ground, Radlett | 2016 |
| 110 | TB Sole | Northamptonshire Second XI v Leicestershire Second XI | Fischer County Ground, Grace Road, Leicester | 2019 |
| 110 | HD Ward | Sussex Second XI v Middlesex Second XI | Uxbridge Cricket Club Ground, Uxbridge | 2025 |
| 109 | BT Foakes | Essex Second XI v Northamptonshire Second XI | County Ground, Northampton | 2014 |
| 109 | LJ Wright | Sussex Second XI v Hampshire Second XI | The Brighton and Hove Jobs County Ground, Hove | 2015 |
| 109* | DL Lloyd | Glamorgan Second XI v Surrey Second XI | Diamond Ground, Cardiff | 2015 |
| 109* | Z Crawley | Kent Second XI v Middlesex Second XI | Polo Farm Sports Club, Canterbury | 2017 |
| 109* | CT Steel | Durham Second XI v Warwickshire Second XI | Roseworth Terrace, Gosforth | 2017 |
| 109* | NR Welch | Leicestershire Second XI v Lancashire Second XI | Aigburth, Liverpool | 2021 |
| 109* | WEL Buttleman | Essex Second XI v Middlesex Second XI | Garon Park, Southend-on-Sea | 2022 |
| 108 | SR Dickson | Kent Second XI v Marylebone Cricket Club Young Cricketers | London Road, High Wycombe | 2015 |
| 108 | DJ Willey | Yorkshire Second XI v Durham Second XI | Brandon Lane, Brandon | 2016 |
| 108* | BJ Dawkins | Kent Second XI v Essex Second XI | The Kent County Cricket Ground, Beckenham | 2025 |
| 107* | JHK Adams | Hampshire Second XI v Surrey Second XI | The Ridge, Purley | 2011 |
| 107 | AM Rossington | Middlesex Second XI v Unicorns A | Uxbridge Cricket Club Ground, Uxbridge | 2013 |
| 107 | TF Smith | Marylebone Cricket Club Young Cricketers v Kent Second XI | London Road, High Wycombe | 2015 |
| 107 | TC Fell | Worcestershire Second XI v Durham Second XI | Burnopfield Cricket Club Ground, Burnopfield | 2019 |
| 107 | NJ Selman | Glamorgan Second XI v Warwickshire Second XI | Edgbaston Foundation Community Sports Ground, Birmingham | 2021 |
| 107* | WAR Fraine | Yorkshire Second XI v Nottinghamshire Second XI | Worksop College Ground, Worksop | 2023 |
| 107 | GH Roderick | Worcestershire Second XI v Warwickshire Second XI | Edgbaston Foundation Community Sports Ground, Birmingham | 2023 |
| 106 | AM Rossington | Essex Second XI v Sussex Second XI | Garon Park, Southend-on-Sea | 2024 |
| 105* | MK Andersson | Middlesex Second XI v Glamorgan Second XI | Spytty Park, Newport | 2018 |
| 105 | TE Albert | Hampshire Second XI v Sussex Second XI | The 1st Central County Ground, Hove | 2021 |
| 105* | IA Cockbain | Gloucestershire Second XI v Northamptonshire Second XI | County Ground, Northampton | 2022 |
| 105 | EN Gay | Northamptonshire Second XI v Glamorgan Second XI | Spytty Park, Newport | 2022 |
| 104 | P Mustard | Durham Second XI v Yorkshire Second XI | Brandon Lane, Brandon | 2016 |
| 104 | LJ Wright | Sussex Second XI v Hampshire Second XI | Blackstone Cricket Club Ground, Blackstone | 2019 |
| 103* | TJ Ravenscroft | Hampshire Second XI v Surrey Second XI | The Ridge, Purley | 2011 |
| 103* | CS MacLeod | Durham Second XI v Yorkshire Second XI | Clifton Park, York | 2014 |
| 103* | SJ Mullaney | Nottinghamshire Second XI v Yorkshire Second XI | Trent College Ground, Long Eaton | 2014 |
| 103* | LS Livingstone | Lancashire Second XI v Unicorns | Aigburth, Liverpool | 2015 |
| 103 | R Gibson | Yorkshire Second XI v Durham Second XI | Windy Hill Lane, Marske-by-the-Sea | 2017 |
| 103 | PI Walter | Essex Second XI v Glamorgan Second XI | The Cloudfm County Ground, Chelmsford | 2018 |
| 103 | CN Ackermann | Leicestershire Second XI v Derbyshire Second XI | Uptonsteel County Ground, Leicester | 2023 |
| 102 | JA Leaning | Yorkshire Second XI v Nottinghamshire Second XI | Trent College Ground, Long Eaton | 2014 |
| 102* | DP Sibley | Warwickshire Second XI v Leicestershire Second XI | Park Road, Loughborough | 2018 |
| 102* | WEL Buttleman | Essex Second XI v Hampshire Second XI | The Cloudfm County Ground, Chelmsford | 2021 |
| 102 | A Prasad | Middlesex Second XI v Hampshire Second XI | The Ageas Bowl, Southampton | 2022 |
| 102 | RM Yates | Warwickshire Second XI v Northamptonshire Second XI | Edgbaston Foundation Community Sports Ground, Birmingham | 2022 |
| 102 | WT Root | Glamorgan Second XI v Worcestershire Second XI | Main Road, Ombersley | 2025 |
| 102 | BD Guest | Derbyshire Second XI v Nottinghamshire Second XI | Repton School Ground, Repton | 2025 |
| 101 | GP Smith | Leicestershire Second XI v Northamptonshire Second XI | County Ground, Northampton | 2012 |
| 101* | KR Brown | Lancashire Second XI v Yorkshire Second XI | Windy Hill Lane, Marske-by-the-Sea | 2013 |
| 101 | DL Lloyd | Glamorgan Second XI v Gloucestershire Second XI | The SWALEC Stadium, Cardiff | 2014 |
| 101 | TP Lewis | Warwickshire Second XI v Worcestershire Second XI | Chester Road North, Kidderminster | 2015 |
| 101 | KR Brown | Lancashire Second XI v Northamptonshire Second XI | County Ground, Northampton | 2017 |
| 101* | MJ Potts | Durham Second XI v Warwickshire Second XI | Scorers, Shirley | 2018 |
| 101* | HC Brook | Yorkshire Second XI v Derbyshire Second XI | Shaw Lane, Barnsley | 2018 |
| 101 | RM Yates | Warwickshire Second XI v Somerset Second XI | Edgbaston Foundation Community Sports Ground, Birmingham | 2025 |
| 100 | CB Cooke | Glamorgan Second XI v Somerset Second XI | County Ground, Taunton | 2013 |
| 100 | LS Livingstone | Lancashire Second XI v Yorkshire Second XI | Windy Hill Lane, Marske-by-the-Sea | 2013 |
| 100* | BL D'Oliveira | Worcestershire Second XI v Warwickshire Second XI | Chester Road North, Kidderminster | 2015 |
| 100* | JHK Adams | Hampshire Second XI v Unicorns | Newclose County Cricket Ground, Newport | 2018 |
| 100 | WAR Fraine | Nottinghamshire Second XI v Northamptonshire Second XI | Worksop College Ground, Worksop | 2018 |
| 100 | JJ Bohannon | Lancashire Second XI v Northamptonshire Second XI | Emirates Old Trafford, Manchester | 2018 |
| 100 | MS Pepper | Essex Second XI v Somerset Second XI | Taunton Vale Sports Club Ground, Taunton | 2019 |
| 100 | EJ Pollock | Warwickshire Second XI v Durham Second XI | Cherry Hill Road, Barnt Green | 2019 |
| 100 | BL D'Oliveira | Worcestershire Second XI v Gloucestershire Second XI | Chester Road North, Kidderminster | 2021 |
| 100 | GA Bartlett | Somerset Second XI v Northamptonshire Second XI | Taunton Vale Sports Club Ground, Taunton | 2021 |
| 100* | OJ Price | Gloucestershire Second XI v Worcestershire Second XI | College Ground, Cheltenham | 2022 |
| 100* | JJ Bohannon | Lancashire Second XI v Nottinghamshire Second XI | The Tyldesleys, Westhoughton | 2023 |
| 100 | BMJ Allison | Essex Second XI v Hampshire Second XI | The Ageas Bowl, Southampton | 2023 |
| 100* | WMH Rhodes | Warwickshire Second XI v Glamorgan Second XI | Spytty Park, Newport | 2023 |
| 100* | BWM Mike | Leicestershire Second XI v Derbyshire Second XI | The Incora County Ground, Derby | 2024 |
